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Selectivity control of CO versus HCOO− production in the visible-light-driven catalytic reduction…

It is highly desirable to discover molecular catalysts with controlled selectivity for visible-light-driven CO2reduction to fuels. In the design of catalysts employing earth-abundant metals, progress has been made for CO production, but formate generation has been observed more rarely. Here, we report a binuclear Co complex bearing a bi-quaterpyridine ligand that can selectively reduce CO2to…

Journal of the American Chemical Society cover

Selective C–F Functionalization of Unactivated Trifluoromethylarenes

Abstract: Fluorinated organic molecules are pervasive within the pharmaceutical and agrochemical industries due to the range of structural and physicochemical properties that fluorine imparts. Currently, the most abundant methods for the synthesis of the aryl–CF2functionality have relied on the deoxyfluorination of ketones and aldehydes using expensive and poorly atom economical reagents. Here, we report a…

Journal of the American Chemical Society cover

Controlling Polymer Composition in O-ATRP and ROP of Vinylcyclopropanes

Abstract: Although radical polymerizations are among the most prevalent methodologies for the synthesis of polymers with diverse compositions and properties, the intrinsic reactivity and selectivity of radical addition challenge the ability to impart control over the polymerization propagation and produce polymers with defined microstructure. Vinylcyclopropanes (VCPs) can be polymerized through radical ring-opening polymerization to produce…

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ARPA-E 10th Energy Innovation Summit Aurora, CO

New Iridium attended the 2019 ARPA-E Summit. This summit brings together energy stakeholders, industry professionals and technology experts from around the world to discuss and address America’s energy challenges in new and innovative ways. This year’s event recognizes 10 years of ARPA-E making ideas into reality and sets the stage for the next decade of…