A Rational Approach to Organo-Photocatalysis. Novel Designs and Structure-Property Relationships
Organic photocatalysts (PCs) are emerging as viable and more sustainable tools with respect to metal…
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Phenoxazines, some of the strongest reducing visible light photocatalysts available, are capable of reducing alkyl and aryl halides via an electron transfer mechanism.
Dihydrophenazine photocatalysts are strong excited state reductants that can reduce alkyl and aryl halides via electron transfer. These PCs oxidize more readily than phenoxazine PCs, even at ground state.
Benzoperylene photocatalysts are among the strongest visible light reductants in existence, enabling even challenging Birch reductions under mild benchtop conditions.
Latest Publications
Organocatalyzed Birch Reduction Driven by Visible Light
The Birch reduction is a powerful synthetic methodology that uses solvated electrons to convert inert…
Configuration mixing upon reorganization of dihedral angle induces rapid intersystem crossing…
A long excited state lifetime is a desirable quality of photocatalysts because it enables a…
Organophotoredox Hydrodefluorination of Trifluoromethylarenes with Translational Applicability…
Abstract: Molecular editing such as insertion, deletion, and single atom exchange in highly functionalized compounds…
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